Correlation of viscosities for alkane, aromatic and alcohol family at high pressure by modified Tait equation

被引:9
|
作者
Xuan Aiguo [1 ]
Wu Yuanxin
Peng Changjun
Ma Pei-sheng
Wang Cunwen
Zhang Liangjun
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] Wuhan Inst Chem & Technol, Dept Chem Engn, Wuhan 430073, Peoples R China
[3] E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China
[4] Hubei Key Lab Novel Chem Reactor & Green Chem Tec, Wuhan 430073, Peoples R China
基金
中国国家自然科学基金;
关键词
viscosity; model; high pressure; Tait equation; activation volume;
D O I
10.1016/S1004-9541(06)60084-0
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new model was proposed to calculate the viscosity of fluids under the pressure ranging from 0.1 to 110MPa by improving the Tait equation, in which the viscosity mu of liquids was linked with activation volume V. The model with two adjustable parameters alpha and beta was applied in calculating viscosities for alkane, aromatic and alcohol family at high pressure. Results show that calculated values of viscosity are in good agreement with the experimental ones, and the average relative deviations for alkanes, aromatics and alcohols are 0.56%, 0.31% and 0.66%, respectively. Besides, the errors correlated by the model proposed in this paper were equivalent to the ones from the pure empirical Tait equation, and obviously superior to those from Eyring equation.
引用
收藏
页码:364 / 370
页数:7
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