Hydrothermal Synthesis and Crystal Structure of a cobalt Complex

被引：0
|
作者：
Gao, Liangjun [1 ]
Song, Wendong [1 ]
机构：
[1] Zhejiang Ocean Univ, Coll Petrochem & Energy Engn, Zhoushan 316000, Peoples R China
来源：
ADVANCES IN CHEMICAL ENGINEERING III, PTS 1-4 | 2013年 / 781-784卷
关键词：
2-4-pyridyl-1H-benzimidazole-5; 6-dicarboxylate; hydrothermal synthesis; cobalt (II) complex; DIMETHYLFORMAMIDE DISOLVATE DIHYDRATE; POLYMERS;
D O I：
10.4028/www.scientific.net/AMR.781-784.571
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A new coordination polymer based on cobalt nitrate and 2-4-pyridyl-1H-benzimidazole-5,6-dicarboxylate (H(2)pbd), namely [Co(pbd)(2)center dot(H2O)(2)](n)center dot n(H2O)(2), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The crystal of the complex crystallizes in triclinic, space group P-1 with a=7.6708(6)angstrom, b=8.0009(8)angstrom, c=12.8348(12)angstrom, alpha=96.4040(10)degrees, beta=102.9480(10)degrees, gamma=112.142(2)degrees, V=694.11(11)angstrom(3), Z=1, C28H22CoN6O12 and F(000)=376.0. The H(2)pbd ligand links the Co (II) atoms into a double stranded chain.
引用
收藏
页码：571 / 575
页数：5
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