A CP/MAS 13C-NMR study of cellulose structure on the surface of refined kraft pulp fibers

被引:38
作者
Hult, EL
Liitiä, T
Maunu, SL
Hortling, B
Iversen, T
机构
[1] STFI, Swedish Pulp & Paper Res Inst, SE-11486 Stockholm, Sweden
[2] Univ Helsinki, Lab Polymer Chem, FIN-00014 Helsinki, Finland
[3] KCL, FIN-02151 Helsinki, Finland
关键词
CP/MAS C-13-NMR; cellulose; fiber surface; kraft pulp; supermolecular structure;
D O I
10.1016/S0144-8617(01)00309-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The average lateral fibril and fibril aggregate dimensions and the crystallinity of the cellulose in a spruce kraft pulp were investigated by CP/MAS C-13-NMR spectroscopy in combination with spectral fitting. Cellulose isolated by chlorite-delignification and acid hydrolysis from fines fractions enriched in surface material and long fiber fractions enriched in bulk material exhibited no major differences in either lateral dimensions or crystallinity index. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:231 / 234
页数:4
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