En route to multicatalysis: kinetic resolution of trans-cycloalkane-1,2-diols via oxidative esterification

被引：15

作者：

Hofmann, Christine ^{[1
]}

Schuler, Soeren M. M. ^{[1
]}

Wende, Raffael C. ^{[1
]}

Schreiner, Peter R. ^{[1
]}

机构：

[1] Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 10期

关键词：

N-HETEROCYCLIC CARBENE; ASYMMETRIC CATALYSIS; PRIMARY ALCOHOLS; MIXED ANHYDRIDE; ALDEHYDES; AMIDATION; ACYLATION; ESTERS; SYSTEM; DIOLS;

D O I：

10.1039/c3cc48584f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate the application of a multicatalyst to the oxidation of a broad variety of aldehydes and subsequent enantioselective esterification of the incipient acids with (+/-)-trans-cycloalkane-1,2- diols. This reaction operates well with a multicatalyst bearing two independent catalytic moieties that provide monoprotected 1,2-diols in one pot.

引用

页码：1221 / 1223

页数：3

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