Synthesis, X-ray structure, and self-assembly of functionalized bis(2,2":6′,2"-terpyridinyl)arenes

被引:36
|
作者
Wang, PS
Moorefield, CN
Newkome, GR [1 ]
机构
[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Goodyear Polymer Ctr, Dept Chem, Akron, OH 44325 USA
关键词
D O I
10.1021/ol0364529
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] meta-Bis(terpyridinyl)phenol has been synthesized from 0-benzyl-3,5-di(formyl)phenol in three steps. Its alkylation afforded a series of bisterpyridinylarenes, which can be self-assembled to afford the corresponding hexametallomacrocycles possessing Fe(II), Zn(II), or Ru(II) connectivity.
引用
收藏
页码:1197 / 1200
页数:4
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