Synthesis, growth, spectral, thermal, mechanical and optical properties of 4-chloro-4′dimethylamino-benzylidene aniline crystal: A third order nonlinear optical material

被引：40

作者：

Leela, S. ^{[1
]}

Ramamurthi, K. ^{[1
]}

Bhagavannarayana, G. ^{[2
]}

机构：

[1] Bharathidasan Univ, Sch Phys, Crystal Growth & Thin Film Lab, Tiruchirappalli 620024, Tamil Nadu, India

[2] Natl Phys Lab, Mat Characterizat Div, New Delhi 110012, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2009年 / 74卷 / 01期

关键词：

Solution growth; Organic compounds; Powder diffraction; Nuclear magnetic resonance; Nonlinear optical materials; ABSORPTION;

D O I：

10.1016/j.saa.2009.05.028

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

An organic nonlinear optical material, 4-chloro-4'dimethylamino-benzylidene aniline (CDMABA), was synthesized by the condensation of the p-chloroaniline and p-dimethylaminobenzaldehyde. Solubility of CDMABA was determined in acetone at different temperatures. Single crystals were grown by the solvent evaporation method from acetone solution at room temperature. Grown crystal was subjected to FTIR FT-Raman and H-1 NMR spectral analyses to confirm the synthesized compound. The range and percentage of optical transmission was ascertained by recording UV-vis-NIR spectrum. Thermal properties were investigated by Thermo Gravimetric, Differential Thermal and Differential Scanning Calorimetric analyses. High Resolution X-ray Diffractometry (HRXRD) was employed to evaluate the perfection of the grown crystal. The third order nonlinear optical parameters (nonlinear refractive index and nonlinear absorption coefficient) were derived by the Z-scan technique. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：78 / 83

页数：6

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