Complex formation and gelation between copolymers containing pendant azobenzene groups and cyclodextrin polymers

被引:109
作者
Takashima, Y [1 ]
Nakayama, T [1 ]
Miyauchi, M [1 ]
Kawaguchi, Y [1 ]
Yamaguchi, H [1 ]
Harada, A [1 ]
机构
[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan
关键词
D O I
10.1246/cl.2004.890
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The copolymers of acrylamide and acrylamide with pendant azobenzene (AzBA-AAm) were prepared by radical polymerization. The association constants of trans-AzBA-AAm copolymers with beta-CD are larger than those of cis-AzBA-AAm copolymers. The trans-AzBA-AAm guest copolymer was found to form supramolecular gels with beta-CD-pAA (pAA; poly(allylamine)) host copolymers in water.
引用
收藏
页码:890 / 891
页数:2
相关论文
共 34 条
  • [1] Azo-dye rotaxanes
    Anderson, S
    Claridge, TDW
    Anderson, HL
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (12): : 1310 - 1313
  • [2] Bender M.L., 1978, Cyclodextrin Chemistry
  • [3] Replisome-mediated DNA replication
    Benkovic, SJ
    Valentine, AM
    Salinas, F
    [J]. ANNUAL REVIEW OF BIOCHEMISTRY, 2001, 70 : 181 - 208
  • [4] A structural basis for processivity
    Breyer, WA
    Matthews, BW
    [J]. PROTEIN SCIENCE, 2001, 10 (09) : 1699 - 1711
  • [5] Synthesis of a cyclodextrin azo dye [3]rotaxane as a single isomer
    Craig, MR
    Claridge, TDW
    Hutchings, MG
    Anderson, HL
    [J]. CHEMICAL COMMUNICATIONS, 1999, (16) : 1537 - 1538
  • [6] Linear and nonlinear optical properties of photochromic molecules and materials
    Delaire, JA
    Nakatani, K
    [J]. CHEMICAL REVIEWS, 2000, 100 (05) : 1817 - 1845
  • [7] The first Janus [2]rotaxane
    Fujimoto, T
    Sakata, Y
    Kaneda, T
    [J]. CHEMICAL COMMUNICATIONS, 2000, (21) : 2143 - 2144
  • [8] Photoswitching of the association of a permethylated α-cyclodextrin-azobenzene dyad forming a Janus [2]pseudorotaxane
    Fujimoto, T
    Nakamura, A
    Inoue, Y
    Sakata, Y
    Kaneda, T
    [J]. TETRAHEDRON LETTERS, 2001, 42 (45) : 7987 - 7989
  • [9] FUKUHARA G, 2003, CHEM LETT, V32, P546
  • [10] PHOTOCONTROL OF MOLECULAR ASSOCIATION ATTAINED BY AZOBENZENE-MODIFIED CYCLODEXTRIN
    FUKUSHIMA, M
    OSA, T
    UENO, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (01) : 15 - 17