Assessing the kinetic model of hydro-distillation and chemical composition of Aquilaria malaccensis leaves essential oil

被引:32
作者
Samadi, Mahtab [1 ]
Abidin, Zurina Zainal [1 ,2 ]
Yunus, Robiah [1 ]
Biak, Dayang Radiah Awang [1 ]
Yoshida, Hiroyuki [1 ]
Lok, Eng Hai [3 ]
机构
[1] Univ Putra Malaysia, Fac Engn, Dept Chem & Environm Engn, Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, AMRC, Fac Engn, Level 7,Tower Block, Serdang 43400, Selangor, Malaysia
[3] Forest Res Inst Malaysia, Kepong 52109, Selangor, Malaysia
关键词
Aquilaria malaccensis; Essential oil; Hydro-distillation; Optimization; Kinetic modeling; SUPERCRITICAL-FLUID EXTRACTION; HYDRODISTILLATION; BIOLUMINESCENCE; FRACTIONATION; ALDEHYDE;
D O I
10.1016/j.cjche.2016.09.006
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study aimed to model the kinetic of hydro-distillation of Aquilaria malaccensis leaves oil in order to understand and optimize the extraction process. In addition, this study, for the first time, aimed to identify the chemical compositions of the A. malaccensis leave-oil. By assessing both first-order kinetic model and the model of simultaneous washing and diffusion, the result indicated that the model of simultaneous washing and diffusion better describes the hydro-distillation mechanism of the essential oil from A. malaccensis leaves. The optimum time, solid to liquid ratio, and the heating power for extracting the highest amount of essential oil were found to be around 3 h, 1: 10 (g.ml(-1)), and 300 W respectively. Yellow essential oil with a strong smell and a yield of 0.05 v/w was extracted by hydro-distillation Clevenger apparatus. Chemical compounds of the essential oil were analyzed using gas chromatography-mass spectroscopy (GC/MS), which resulted in identification of 42 compounds that constitute 93% of essential oil. Among the identified components, Pentadecanal (32.082%), 9-Octadecenal, (Z) (15.894%), and Tetradecanal (6.927%) were the major compounds. Considering the fact that all the identified major components possess pesticidal properties, A. malaccensis leaves can be regarded as a promising natural source for producing pesticides. (C) 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
引用
收藏
页码:216 / 222
页数:7
相关论文
共 35 条
[31]  
Suresh K., 2008, ETHNOBOT LEAFL, V12, P586
[32]   IDENTIFICATION OF POSSIBLE SEX-PHEROMONE OF THE YELLOW STEM BORER MOTH, SCIRPOPHAGA-INCERTULAS (WALKER) (LEPIDOPTERA, PYRALIDAE) [J].
TATSUKI, S ;
SUGIE, H ;
USUI, K ;
FUKAMI, J ;
HOEDAYA, M ;
SUMARTAPUTRA ;
KUSWADI, AN .
APPLIED ENTOMOLOGY AND ZOOLOGY, 1985, 20 (03) :357-359
[33]   EVIDENCE FOR TETRADECANAL AS THE NATURAL ALDEHYDE IN BACTERIAL BIOLUMINESCENCE [J].
ULITZUR, S ;
HASTINGS, JW .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1979, 76 (01) :265-267
[34]   EFFECTS OF ALDEHYDE AND INTERNAL IONS ON BIOLUMINESCENCE EXPRESSION OF PHOTOBACTERIUM-PHOSPHOREUM [J].
WATANABE, H ;
INABA, H ;
HASTINGS, JW .
ARCHIVES OF MICROBIOLOGY, 1991, 156 (01) :1-4
[35]  
Zaridah MZ, 2006, J TROP FOR SCI, V18, P74