Cobalt-Catalyzed Decarboxylative 2-Benzoylation of Oxazoles and Thiazoles with α-Oxocarboxylic Acids

被引：67
作者：
Yang, Ke [1 ]
Chen, Xinyong [1 ]
Wang, Yuqi [1 ]
Li, Wanqing [1 ]
Kadi, Adnan A. [2 ]
Fun, Hoong-Kun [2 ]
Sun, Hao [1 ]
Zhang, Yan [1 ,2 ]
Li, Guigen [1 ]
Lu, Hongjian [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Chem & BioMed Sci, Nanjing 210093, Jiangsu, Peoples R China
[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 21期
基金：
中国国家自然科学基金;
关键词：
C-H ACTIVATION; CARBON-CARBON BONDS; O-METHYL KETOXIMES; ORTHO-ACYLATION; DIRECT ARYLATION; BENZOIC-ACIDS; DESULFITATIVE ARYLATION; DIRECT C2-ALKYLATION; ARYLGLYOXYLIC ACIDS; AZOLES;
D O I：
10.1021/acs.joc.5b01450
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cobalt-catalyzed decarboxylative cross-coupling of oxazoles and thiazoles with alpha-oxocarboxylic acids was developed through an sp(2) C-H bond functionalization process. This work represents the first example of cobalt-catalyzed decarboxylative C-H bond functionalization and provides an efficient means of building some important bioactive heteroaryl ketone derivatives.
引用
收藏
页码：11065 / 11072
页数：8
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