Detection of argan oil adulteration with vegetable oils by high-performance liquid chromatography-evaporative light scattering detection

被引:73
作者
Salghi, Rachid [1 ]
Armbruster, Wolfgang [2 ]
Schwack, Wolfgang [2 ]
机构
[1] Univ Ibn Zohr, Ecole Natl Sci Appl, Equipe Genie Environm & Biotechnol, Agadir, Morocco
[2] Univ Stuttgart Hohenheim, Inst Food Chem, D-70599 Stuttgart, Germany
关键词
Virgin argan oil; Vegetable oils; Adulteration; HPLC-ELSD; HPLC-RID; Triacylglycerols; OLIVE OIL; FATTY-ACIDS; APCI-MS; TRIACYLGLYCEROLS; INTERVENTION; AUTHENTICITY; VALIDATION; HPLC; FOOD;
D O I
10.1016/j.foodchem.2013.12.084
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Triacylglycerol profiles were selected as indicator of adulteration of argan oils to carry out a rapid screening of samples for the evaluation of authenticity. Triacylglycerols were separated by high-performance liquid chromatography-evaporative light scattering detection. Different peak area ratios were defined to sensitively detect adulteration of argan oil with vegetable oils such as sunflower, soy bean, and olive oil up to the level of 5%. Based on four reference argan oils, mean limits of detection and quantitation were calculated to approximately 0.4% and 1.3%, respectively. Additionally, 19 more argan oil reference samples were analysed by high-performance liquid chromatography-refractive index detection, resulting in highly comparative results. The overall strategy demonstrated a good applicability in practise, and hence a high potential to be transferred to routine laboratories. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:387 / 392
页数:6
相关论文
共 22 条
[1]  
Charrouf Z, 2008, NAT PROD COMMUN, V3, P283
[2]   Consumption of argan oil may have an antiatherogenic effect by improving paraoxonase activities and antioxidant status: Intervention study in healthy men [J].
Cherki, M ;
Derouiche, A ;
Drissi, A ;
El Messal, M ;
Bamou, Y ;
Idrissi-Ouadghiri, A ;
Khalil, A ;
Adlouni, A .
NUTRITION METABOLISM AND CARDIOVASCULAR DISEASES, 2005, 15 (05) :352-360
[3]   Argan oil: Which benefits on cardiovascular diseases? [J].
Cherki, Mounia ;
Berrougui, Hicham ;
Drissi, Anas ;
Adlouni, Ahmed ;
Khalil, Abdelouahed .
PHARMACOLOGICAL RESEARCH, 2006, 54 (01) :1-5
[4]   Effectiveness of determinations of fatty acids and triglycerides for the detection of adulteration of olive oils with vegetable oils [J].
Christopoulou, E ;
Lazaraki, M ;
Komaitis, M ;
Kaselimis, K .
FOOD CHEMISTRY, 2004, 84 (03) :463-474
[5]   Nutritional intervention study with argan oil in man: Effects on lipids and apolipoproteins [J].
Derouiche, A ;
Cherki, M ;
Drissi, A ;
Bamou, Y ;
El Messal, M ;
Idrissi-Oudghiri, A ;
Lecerf, JM ;
Adlouni, A .
ANNALS OF NUTRITION AND METABOLISM, 2005, 49 (03) :196-201
[6]   Evidence of hypolipemiant and antioxidant properties of argan oil derived from the argan tree (Arganial spinosa) [J].
Drissi, A ;
Girona, J ;
Cherki, M ;
Godàs, G ;
Derouiche, A ;
El Messal, M ;
Saile, R ;
Kettani, A ;
Solà, R ;
Masana, L ;
Adlouni, A .
CLINICAL NUTRITION, 2004, 23 (05) :1159-1166
[7]   DETECTION OF OLIVE OIL ADULTERATION BY MEASURING ITS AUTHENTICITY FACTOR USING REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].
ELHAMDY, AH ;
ELFIZGA, NK .
JOURNAL OF CHROMATOGRAPHY A, 1995, 708 (02) :351-355
[8]   Optimization and application of methods of triacylglycerol evaluation for characterization of olive oil adulteration by soybean oil with HPLC-APCI-MS-MS [J].
Fasciotti, Maira ;
Pereira Netto, Annibal D. .
TALANTA, 2010, 81 (03) :1116-1125
[9]   Adulteration detection of argan oil by inductively coupled plasma optical emission spectrometry [J].
Gonzalvez, A. ;
Armenta, S. ;
de la Guardia, M. .
FOOD CHEMISTRY, 2010, 121 (03) :878-886
[10]  
Harhar H, 2010, NAT PROD COMMUN, V5, P1799