Aluminum anode for aluminum-air battery - Part II: Influence of In addition on the electrochemical characteristics of Al-Zn alloy in alkaline solution

被引:139
作者
Park, In-Jun [1 ]
Choi, Seok-Ryul [1 ]
Kim, Jung-Gu [1 ]
机构
[1] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, 300 Chunchun Dong, Suwon 440746, South Korea
基金
新加坡国家研究基金会;
关键词
Aluminum-air battery; Anode; Aluminum alloy; Discharge performance; Battery resistance; GA-0.1; SN-0.5; MN; CHLORIDE SOLUTIONS; SN ALLOYS; IMPEDANCE SPECTROSCOPY; POTASSIUM HYDROXIDE; SODIUM-CHLORIDE; NACL SOLUTION; ZINC; BEHAVIOR; IONS;
D O I
10.1016/j.jpowsour.2017.04.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Effects of Zn and In additions on the aluminum anode for Al-air battery in alkaline solution are examined by the self-corrosion rate, cell voltage, current-voltage characteristics, anodic polarization, discharge performance and AC impedance measurements. The passivation behavior of Zn-added anode during anodic polarization decreases the discharge performance of Al-air battery. The addition of In to Al-Zn anode reduces the formation of Zn passivation film by repeated adsorption and desorption behavior of In ion onto anode surface. The attenuated Zn passive layer by In ion attack leads to the improvement of discharge performance of Al-air battery. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:47 / 55
页数:9
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