Stereospecific C-H Oxidation with H2O2 Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

被引：221

作者：

Gomez, Laura ^{[1
]}

Garcia-Bosch, Isaac ^{[1
]}

Company, Anna ^{[1
]}

Benet-Buchholz, Jordi ^{[2
]}

Polo, Alfonso ^{[1
]}

Sala, Xavier ^{[2
]}

Ribas, Xavi ^{[1
]}

Costas, Miquel ^{[1
]}

机构：

[1] Univ Girona, Dept Quim, Campus Montilivi, Girona 17071, Spain

[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 31期

关键词：

catalyst design; homogeneous catalysis; hydrogen peroxide; iron; oxidation; ALKANE HYDROXYLATION; EFFICIENT; COMPLEX; BONDS; ACID; EPOXIDATION; METHYL(TRIFLUOROMETHYL)DIOXIRANE; OXYFUNCTIONALIZATION; FUNCTIONALIZATION; OXYGENATION;

D O I：

10.1002/anie.200901865

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5720 / 5723

页数：4

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