Stereospecific C-H Oxidation with H2O2 Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

被引：221
|
作者：
Gomez, Laura [1 ]
Garcia-Bosch, Isaac [1 ]
Company, Anna [1 ]
Benet-Buchholz, Jordi [2 ]
Polo, Alfonso [1 ]
Sala, Xavier [2 ]
Ribas, Xavi [1 ]
Costas, Miquel [1 ]
机构：
[1] Univ Girona, Dept Quim, Campus Montilivi, Girona 17071, Spain
[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 31期
关键词：
catalyst design; homogeneous catalysis; hydrogen peroxide; iron; oxidation; ALKANE HYDROXYLATION; EFFICIENT; COMPLEX; BONDS; ACID; EPOXIDATION; METHYL(TRIFLUOROMETHYL)DIOXIRANE; OXYFUNCTIONALIZATION; FUNCTIONALIZATION; OXYGENATION;
D O I：
10.1002/anie.200901865
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5720 / 5723
页数：4
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