Atom-Efficient, Palladium-Catalyzed Stille Coupling Reactions of Tetraphenylstannane with Aryl Iodides or Aryl Bromides in Polyethylene Glycol 400 (PEG-400)

被引：41
作者：
Zhou, Wen-Jun [1 ]
Wang, Ke-Hu [1 ]
Wang, Jin-Xian [1 ,2 ]
机构：
[1] NW Normal Univ, Dept Chem, Inst Chem, Lanzhou 730070, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 09期
关键词：
aryl bromides; aryl iodides; atom efficiency; polyethylene glycol 400 (PEG-400); Stille coupling; tetraphenylstannane; NONIONIC LIQUID SOLVENT; ORGANOTIN REAGENTS; ALPHA-PYRONES; HALIDES; SUZUKI; CHLORIDES; CARBON; HYDROGENATION; MECHANISM; OXIDATION;
D O I：
10.1002/adsc.200800754
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The Stille coupling of tetraphenylstannane with aryl iodides or aryl bromides using the bis(triphenylphosphine)palladium dichloride/sodium acetate/polyethylene glycol 400 [PdCl2(PPh3)(2)/NaOAc/PEG-400] catalytic system at 100 degrees C has been developed. The reactions were carried out in an atom-efficient way, as 4 equivalents of aryl iodides or aryl bromides coupled effectively with 1 equivalent of tetraphenylstannane to furnish 4 equivalents of the corresponding functionalized biaryls in high yields.
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页码：1378 / 1382
页数：5
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