Investigation of structural and photocatalytic behavior of Bi13B1-2xVxPxO20.95+2x (0 < x ≤ 0.5)

被引:35
作者
Barebita, Hanane [1 ]
Naciri, Yassine [2 ]
Ferraa, Soumya [1 ]
Nimour, Abderrazak [1 ]
Guedira, Taoufiq [1 ]
机构
[1] Univ IbnTofail, Fac Sci, Lab Mat Electrochem & Environm, BP 133, Kenitra 14000, Morocco
[2] Ibn Zohr Univ, Fac Sci, Lab Mat & Environm, Agadir, Morocco
关键词
Bismuth vanadate; Selenite-type; Photocatalytic activity; RhB; Degradation; LIGHT-INDUCED DEGRADATION; METHYLENE-BLUE; RHODAMINE-B; GLASS; REMOVAL; GAMMA-BI2O3; IRRADIATION; BIVO4; RAMAN; DYE;
D O I
10.1016/j.solidstatesciences.2020.106389
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The aim of this study was to investigate the photocatalytic activity of polycrystalline phases of bismuth vanadate of formula Bi13B1-2xVx PxO20.95+2x with x = 0, 0.1, 0.2, 0.25, 0.4 and 0.5. The catalysts were prepared by solid state method at 700 degrees C and were further characterized using a variety characterization techniques such X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and Xray energy dispersion spectroscopy (EDS). The photocatalytic experiments were carried out using rhodamine B (RhB) as a model pollutant; the UV-visible spectrometry was used to analyze the evolution of dye degradation. The obtained photocatalytic results clearly indicated that all as-prepared photocatalysts exhibited higher photocatalytic activities than that of the pure Bi13B1-2xVx PxO20.95+2x with x = 0. The best degradation performance is obtained when using the Bi13B1-2xVx PxO20.95+2x with x = 0.2 catalyst. Moreover, the complete degradation of RhB can be achieved after 180 min of UV irradiation in the presence of this catalyst.
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页数:8
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