Bisglycine-substituted ferrocene conjugates

被引：0
|
作者：
Kraatz, HB [1 ]
机构：
[1] Univ Saskatchewan, Dept Chem, Saskatoon, SK S7N 5C9, Canada
来源：
MACROMOLECULAR SYMPOSIA | 2004年 / 209卷
关键词：
ferrocene; hydrogen bonding peptide; supramolecular assembly;
D O I：
10.1002/masy.200450512
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The solid state structures of three bissubstituted glycine ferrocene conjugates are described allowing a direct comparison of the structural parameters. Whereas the fully protected glycine ester Fc(Gly-OEt)(2) adopts a 1,3'-conformation leading exclusively to intermolecular H-bond formation, the free acid Fc(Gly-OH)(2) adopts the more compact 1,3'-comformation with intramolecular H-bonding. The same intramolecular H-bonding pattern is adopted by the glycine ferrocenophane Fc(Gly-CSA)(2).
引用
收藏
页码：177 / 183
页数：7
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