Synthesis of (pentamethylcyclopentadienyl)tantalum sulfido complexes via C-S bond cleavage of triphenylmethanethiolate and formation of a novel trithioborato ligand

被引：38

作者：

Kawaguchi, H ^{[1
]}

Tatsumi, K ^{[1
]}

机构：

[1] NAGOYA UNIV,FAC SCI,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 03期

关键词：

D O I：

10.1021/om960864m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Cp*TaCl4 with triphenyl-methanethiol via C-S bond cleavage gave rise to Cp*TaCl(S)(SCPh(3)) (1), which was treated with LiSR, Li2S, and NaBH4 to afford Cp*TaS(SR)(SCPh(3)) (R = CPh(3) (2), CMe(3) (3)), [Cp*Ta(S)(3)Li-2(THF)(2)](2) (4), and Cp*Ta-3(3)(S)(3)(S3BH) (5), respectively. The crystal structures of 1 and 5 were determined by X-ray diffraction.

引用

页码：307 / 309

页数：3

共 50 条

[31] C-S Bond Cleavage, Redox Reactions, and Dioxygen Activation by Nonheme Dicobalt(II) Complexes
Jana, Manish
Majumdar, Amit
INORGANIC CHEMISTRY, 2018, 57 (02) : 617 - 632
[32] Ligand-Free C-S Bond Formation Catalyzed by Copper(I) Oxide
Xu, Hua-Jian
Zhao, Xiao-Yang
Fu, Yao
Feng, Yi-Si
SYNLETT, 2008, (19) : 3063 - 3067
[33] Base-Promoted Selective Synthesis of Alkynyl Sulfides via C-S Bond Cleavage of Alkynyl Sulfonium Salts
Wang, Ziyu
Su, Mengke
Xu, Hanmiao
Zhou, Junqi
Wen, Jian
ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (10) : 2264 - 2269
[34] DszA Catalyzes C-S Bond Cleavage through N5-Hydroperoxyl Formation
Ferreira, Pedro
Neves, Rui P. P.
Miranda, Filipa P.
Cunha, Ana V.
Havenith, Remco W. A.
Ramos, Maria J.
Fernandes, Pedro A.
JOURNAL OF CHEMICAL INFORMATION AND MODELING, 2024, 64 (10) : 4218 - 4230
[35] Reductase of Mutanobactin Synthetase Triggers Sequential C-C Macrocyclization, C-S Bond Formation, and C-C Bond Cleavage
Wang, Min
Xie, Zhoujie
Tang, Shoubin
Chang, Ee Ling
Tang, Yue
Guo, Zhengyan
Cui, Yinglu
Wu, Bian
Ye, Tao
Chen, Yihua
ORGANIC LETTERS, 2020, 22 (03) : 960 - 964
[36] Transition-metal-free synthesis of imidazobenzothiazines via domino C-S/C-N bond formation
Tu, Xingzhao
Zhou, Lihong
Li, Zhijie
Lei, Ning
Zeng, Qingle
MONATSHEFTE FUR CHEMIE, 2014, 145 (12): : 1925 - 1931
[37] Transition-metal-free synthesis of imidazobenzothiazines via domino C-S/C-N bond formation
Xingzhao Tu
Lihong Zhou
Zhijie Li
Ning Lei
Qingle Zeng
Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 1925 - 1931
[38] Thioethers as Dichotomous Electrophiles for Site-Selective Silylation via C-S Bond Cleavage
Chen, Shuai
Guo, Xueying
Hou, Haoran
Geng, Shasha
Liu, Zhengli
He, Yun
Xue, Xiao-Song
Feng, Zhang
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (25)
[39] Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage
Uetake, Yuta
Niwa, Takashi
Hosoya, Takamitsu
ORGANIC LETTERS, 2016, 18 (11) : 2758 - 2761
[40] C-S and C-Se Bond Formation at Bridging Vinyliminium Ligands in Diiron Complexes
Marchetti, Fabio
Zacchini, Stefano
Zanotti, Valerio
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (29) : 5145 - 5152

← 1 2 3 4 5 →