Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4

被引：126

作者：

Hartmann, Martin ^{[1
]}

Boehme, Ulrike ^{[1
]}

Hovestadt, Maximilian ^{[1
]}

Paula, Carolin ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Erlangen Catalysis Resource Ctr, D-91058 Erlangen, Germany

来源：

LANGMUIR | 2015年 / 31卷 / 45期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; METAL-ORGANIC FRAMEWORK; MIXED-MATRIX MEMBRANES; HYDROCARBON SEPARATIONS; INDUCED AMORPHIZATION; KINETIC SEPARATION; GAS ADSORPTION; SIEVE ZIF-8; DIFFUSION; PROPANE;

D O I：

10.1021/acs.langmuir.5b02907

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The microporous zeolitic imidazolate framework ZIF-4 has been synthesized, and its ethylene/ethane and propylene/propane separation potentials have been evaluated by single-component adsorption isotherms and breakthrough experiments of the respective binary mixtures. In all experiments, a higher selectivity for the paraffin is observed that is manifested by a steeper equilibrium isotherm as well as a later breakthrough in the fixed-bed adsorber experiments. Microporous interesting for cyclic adsorption processes such as pressure-swing adsorption (PSA).

引用

页码：12382 / 12389

页数：8

共 52 条

[1] Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes [J].

Askari, Mohammad ;

Chung, Tai-Shung .

JOURNAL OF MEMBRANE SCIENCE, 2013, 444 :173-183

[2] High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites [J].

Bae, Youn-Sang ;

Lee, Chang Yeon ;

Kim, Ki Chul ;

Farha, Omar K. ;

Nickias, Peter ;

Hupp, Joseph T. ;

Nguyen, SonBinh T. ;

Snurr, Randall Q. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1857-1860

[3] Adsorption of Ethane, Ethylene, Propane, and Propylene on a Magnesium-Based Metal-Organic Framework [J].

Bao, Zongbi ;

Alnemrat, Sufian ;

Yu, Liang ;

Vasiliev, Igor ;

Ren, Qilong ;

Lu, Xiuyang ;

Deng, Shuguang .

LANGMUIR, 2011, 27 (22) :13554-13562

[4] NONISOTHERMAL DESORPTION BY GAS PURGE OF SINGLE SOLUTES IN FIXED-BED ADSORBERS .1. EQUILIBRIUM THEORY [J].

BASMADJIAN, D ;

HA, KD ;

PAN, CY .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :328-340

[5] Zeolitic imidazolate frameworks for separation of binary mixtures of CO2, CH4, N2 and H2: A computer simulation investigation [J].

Battisti, Anna ;

Taioli, Simone ;

Garberoglio, Giovanni .

MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 143 (01) :46-53

[6] Flexibility of zeolitic imidazolate framework structures studied by neutron total scattering and the reverse Monte Carlo method [J].

Beake, E. O. R. ;

Dove, M. T. ;

Phillips, A. E. ;

Keen, D. A. ;

Tucker, M. G. ;

Goodwin, A. L. ;

Bennett, T. D. ;

Cheetham, A. K. .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2013, 25 (39)

[7] Ball-Milling-Induced Amorphization of Zeolitic Imidazolate Frameworks (ZIFs) for the Irreversible Trapping of Iodine [J].

Bennett, Thomas D. ;

Saines, Paul J. ;

Keen, David A. ;

Tan, Jin-Chong ;

Cheetham, Anthony K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (22) :7049-7055

[8] Thermal Amorphization of Zeolitic Imidazolate Frameworks [J].

Bennett, Thomas D. ;

Keen, David A. ;

Tan, Jin-Chong ;

Barney, Emma R. ;

Goodwin, Andrew L. ;

Cheetham, Anthony K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (13) :3067-3071

[9] Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks [J].

Bennett, Thomas D. ;

Cao, Shuai ;

Tan, Jin Chong ;

Keen, David A. ;

Bithell, Erica G. ;

Beldon, Patrick J. ;

Friscic, Tomislav ;

Cheetham, Anthony K. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (37) :14546-14549

[10] Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4) [J].

Bennett, Thomas D. ;

Simoncic, Petra ;

Moggach, Stephen A. ;

Gozzo, Fabia ;

Macchi, Piero ;

Keen, David A. ;

Tan, Jin-Chong ;

Cheetham, Anthony K. .

CHEMICAL COMMUNICATIONS, 2011, 47 (28) :7983-7985

← 1 2 3 4 5 6 →