Direct Decomposition of Nitrous Oxide to Nitrogen by In Situ Oxygen Removal with a Perovskite Membrane

被引：124
作者：
Jiang, Heqing [3 ]
Wang, Haihui [1 ]
Liang, Fangyi [3 ]
Werth, Steffen [4 ]
Schiestel, Thomas [2 ]
Caro, Juergen [3 ]
机构：
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] Fraunhofer Inst Interfacial Engn & Biotechnol IGB, D-70569 Stuttgart, Germany
[3] Leibniz Univ Hannover, J Heyrovsky Inst Phys Chem & Electrochem, D-30167 Hannover, Germany
[4] Uhde GmbH, D-44141 Dortmund, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 16期
关键词：
membrane reactors; N2O decomposition; partial oxidation of methane; perovskite; syngas; SELECTIVE CATALYTIC-REDUCTION; DIRECT N2O DECOMPOSITION; HOLLOW-FIBER MEMBRANES; FE-MFI; OXIDATION; METHANE; NOBLE; GASES; METAL; NO;
D O I：
10.1002/anie.200804582
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Direct decomposition of N2O to N2 using perovskite hollow fiber membranes is achieved by combination with in situ oxygen removal (see picture). A coupled partial methane oxidation allows N2-free synthesis gas to be obtained. This sustainable process combines N2O removal with the simultaneous production of valuable chemicals. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2983 / 2986
页数：4
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