Fiber Spinning of Polyacrylonitrile Grafted Soy Protein in an Ionic Liquid/DMSO Mixture Solvent

被引：19

作者：

Deng, Shifeng ^{[1
,2
]}

Cheng, Jia ^{[1
]}

Guo, Xiaojie ^{[1
]}

Jiang, Long ^{[3
]}

Zhang, Jinwen ^{[1
]}

机构：

[1] Washington State Univ, Composite Mat & Engn Ctr, Pullman, WA 99164 USA

[2] E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Specially Funct Polymer Mat & Related Tec, Minist Educ, Shanghai 200237, Peoples R China

[3] N Dakota State Univ, Dept Mech Engn, Fargo, ND 58108 USA

来源：

JOURNAL OF POLYMERS AND THE ENVIRONMENT | 2014年 / 22卷 / 01期

关键词：

Ionic liquids; Soy protein; Wet spinning; Polyacrylonitrile; Grafting; MECHANICAL-PROPERTIES; HYDROGEL FIBERS; DISSOLUTION; ISOLATE;

D O I：

10.1007/s10924-013-0617-8

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The effects of ionic liquid BMIMCL (1-buthyl-3-methyl-imidazolium-chloride) on the solution of soy protein isolate (SPI) were first studied. In situ polymerization of acrylonitrile monomer in the presence of SPI was conducted in a BMIMCL/dimethyl sulfoxide (DMSO) mixture solvent to produce SPI-g-PAN. This graft polymer was blended with pure PAN in BMIMCL/DMSO (1:5) and spun into fiber using a wet spinning method. The effects of SPI content and solution temperature on the viscoelasticity of the spinning dope were studied. FTIR, DSC and solution studies were used to confirm the grafting of PAN. Microstructure and mechanical properties of the spun fibers under different draw ratios were investigated.

引用

页码：17 / 26

页数：10

共 30 条

[1] Electrospun Hybrid Soy Protein/PVA Fibers
Cho, Daehwan
Nnadi, Olivia
Netravali, Anil
Joo, Yong Lak
[J]. MACROMOLECULAR MATERIALS AND ENGINEERING, 2010, 295 (08) : 763 - 773
[2] Protein solubilising and stabilising ionic liquids
Fujita, K
MacFarlane, DR
Forsyth, M
[J]. CHEMICAL COMMUNICATIONS, 2005, (38) : 4804 - 4806
[3] Haibo X, 2005, GREEN CHEM, V7, P606
[4] Huang HC, 1995, JAOCS, V12, P1453
[5] Dynamic mechanical properties of soy protein filled elastomers
Jong, L
[J]. JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2005, 13 (04) : 329 - 338
[6] STUDIES ON THE RELATIONSHIP BETWEEN THE DYNAMIC VISCOELASTIC BEHAVIOR AND SPINNABILITY OF SOY PROTEIN
KATSUTA, K
HAYAKAWA, I
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1984, 48 (03): : 727 - 731
[7] Dissolution of wood in ionic liquids
Kilpelainen, Ilkka
Xie, Haibo
King, Alistair
Granstrom, Mari
Heikkinen, Sami
Argyropoulos, Dimitris S.
[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (22) : 9142 - 9148
[8] Application of ionic liquids as solvents for polymerization processes
Kubisa, P
[J]. PROGRESS IN POLYMER SCIENCE, 2004, 29 (01) : 3 - 12
[9] Characterization of stearic acid modified soy protein isolate resin and ramie fiber reinforced 'green' composites
Lodha, P
Netravali, AN
[J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (7-8) : 1211 - 1225
[10] Characterization of interfacial and mechanical properties of "green" composites with soy protein isolate and ramie fiber
Lodha, P
Netravali, AN
[J]. JOURNAL OF MATERIALS SCIENCE, 2002, 37 (17) : 3657 - 3665

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