Solid state lithium ionic conducting thin film Li1.4Al0.4Ge1.6(PO4)3 prepared by tape casting

被引：72
|
作者：
Zhang, Ming [1 ]
Huang, Zheng [1 ]
Cheng, Junfang [1 ]
Yamamoto, Osamu [2 ]
Imanishi, Nobuyuki [2 ]
Chi, Bo [1 ]
Pu, Jian [1 ]
Li, Jian [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, Ctr Fuel Cell Innovat, State Key Lab Mat Proc & & Mould Technol, Wuhan 430074, Peoples R China
[2] Mie Univ, Fac Engn, Dept Chem, Tsu, Mie 5148507, Japan
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2014年 / 590卷
关键词：
Solid electrolyte; LAGP; Lithium air batteries; Tape casting; Water stable lithium electrolyte; GLASS-CERAMICS; ELECTROLYTE; BATTERIES; ANODE; COMPOSITE;
D O I：
10.1016/j.jallcom.2013.12.100
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solid-state lithium ionic conducting ceramic thin film Li1.4Al0.4Ge1.6(PO4)(3) is prepared by tape casting method. The thermal decomposition of the green tape is investigated by TG/DTA analysis. And the sintering parameters are optimized in air. The resultant sample shows a total lithium ionic conductivity of 3.38 x 10(-4) S cm(-1) at 25 degrees C and activation energy of 30.57 kJ mol(-1). The thickness of the tape sheet can be controlled to be about 75 lm. The ionic conductivity of the prepared sample reported in this study is comparable with those reported for commercial LATP plate, showing the potential application for lithium-air batteries. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：147 / 152
页数：6
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