The recent progress of synergistic supramolecular polymers: preparation, properties and applications

被引:56
作者
Huo, Yufeng [1 ]
He, Zhenfeng [1 ]
Wang, Chao [2 ]
Zhang, Lei [1 ]
Xuan, Qianyu [1 ]
Wei, Suying [3 ]
Wang, Yanhong [1 ]
Pan, Duo [4 ,5 ]
Dong, Binbin [4 ]
Wei, Renbo [6 ]
Naik, Nithesh [7 ]
Guo, Zhanhu [5 ]
机构
[1] North Univ China, Sch Chem Engn & Technol, Taiyuan 030051, Peoples R China
[2] North Univ China, Coll Mat Sci & Engn, Taiyuan 030051, Peoples R China
[3] Lamar Univ, Dept Chem & Biochem, Beaumont, TX 77710 USA
[4] Zhengzhou Univ, Natl Engn Res Ctr Adv Polymer Proc Technol, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou, Peoples R China
[5] Univ Tennessee, Dept Chem & Biomol Engn, Integrated Composites Lab ICL, Knoxville, TN 37996 USA
[6] Northwest Univ, Sch Chem Engn, Xian 710069, Peoples R China
[7] Manipal Acad Higher Educ, Manipal Inst Technol, Dept Mech & Mfg Engn, Manipal 576104, Karnataka, India
基金
中国国家自然科学基金;
关键词
PI-PI STACKING; HYPERBRANCHED POLYMERS; MOLECULAR RECOGNITION; THERMAL RESPONSIVENESS; CHARGE-TRANSFER; CHEMISTRY; POLYMERIZATION; COMPLEXES; SHAPE; DRUG;
D O I
10.1039/d0cc07247h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular polymers have the combined properties of both traditional polymers and supramolecules. They are generally formed via the self-assembled polymerization driven noncovalent interactions such as hydrogen bonding, pi-pi stacking, metal coordination, and host-guest interaction between building blocks. The driving force for the formation of supramolecular polymers has changed from single noncovalent interactions to multiple noncovalent interactions. The advantages of multiple noncovalent interactions driving the formation of supramolecular polymers are reviewed from four aspects: polymer construction, the enhancement of bonding strength, properties and topological structure. The applications are illustrated with detailed examples including self-healing, drug delivery, bioimaging, biomedicine, environmental sensing and electronics.
引用
收藏
页码:1413 / 1429
页数:17
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