Chevalierinosides B (1) and C (2), two new isoflavonoid glycosides, characterized as biochanin A 7-O-[beta-D-apiofuranosyl-(1 -> 2)-beta-D-glucopyranoside] and genistein 7-O-[beta-D-apiofuranosyl-(1 -> 2)-beta-D-glucopyranoside], together with the known isoflavonoids, chevalierinoside A (3) and genistein 7-O-beta-D-glucopyranoside (4), kaempferol 3-O-beta-D-glucopyranoside (5) and triterpenes, friedelin (6), betulinic acid (7), 30-oxobetulinic acid (8), 30-hydroxybetulinic acid (9), were isolated from the stem bark of Antidesma laciniatum Muell. Arg. (syn. Antidesma chevalieri Beille). Their structures were established by direct interpretation of their spectral data, mainly HR-TOFESIMS, 1D-NMR (H-1, C-13 and DEPT) and 2D-NMR (COSY, NOESY, TOCSY, HSQC and HMBC), and by comparison with the literature. (C) 2014 Phytochemical Society of Europe. Published by Elsevier B.V. All rights reserved.