Interfacial electronic states of an anthracene derivative deposited on a SiO2/Si substrate

被引:3
作者
Sasaki, Hiroyuki
Wakayama, Yutaka
Chikyow, Toyohiro
Imamura, Masaki
Tanaka, Akinori
Kobayashi, Kenji
机构
[1] NIMS, Nanomat Lab, Tsukuba, Ibaraki 3050044, Japan
[2] JST, JCORP, Nanoscale Quantum Conductor Array Project, Tsukuba, Ibaraki 3050044, Japan
[3] Kobe Univ, Grad Sch Sci & Technol, Nada Ku, Kobe, Hyogo 6578501, Japan
[4] Kobe Univ, Dept Mech Engn, Nada Ku, Kobe, Hyogo 6578501, Japan
[5] Shizuoka Univ, Dept Chem, Shizuoka 4228529, Japan
关键词
surfaces and interfaces; organic semiconductors; electronic states; photoelectron spectroscopies;
D O I
10.1016/j.ssc.2006.05.039
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The interfacial electronic states of an anthracene derivative (9,10-bis (methylthio) anthracene) on a SiO2/Si(100) substrate were studied using ultraviolet photoelectron spectroscopy (UPS). From the UPS measurements, the work function of the sample surface was found to decrease with increasing molecular coverage in the sub-monolayer range. It is concluded that an interfacial electronic dipole (about 0.34 eV) forms at the molecule/SiO2 interface and decreases the effective work function. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:153 / 156
页数:4
相关论文
共 18 条
[1]   PHOTOEMISSION-STUDY OF SIOX (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2) ALLOYS [J].
BELL, FG ;
LEY, L .
PHYSICAL REVIEW B, 1988, 37 (14) :8383-8393
[2]   Electrostatic field and partial Fermi level pinning at the pentacene-SiO2 interface [J].
Chen, LW ;
Ludeke, R ;
Cui, XD ;
Schrott, AG ;
Kagan, CR ;
Brus, LE .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (05) :1834-1838
[3]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[4]  
2-9
[5]  
Ishii H, 1999, ADV MATER, V11, P605, DOI 10.1002/(SICI)1521-4095(199906)11:8<605::AID-ADMA605>3.0.CO
[6]  
2-Q
[7]   LOW-TEMPERATURE SURFACE CLEANING OF SILICON AND ITS APPLICATION TO SILICON MBE [J].
ISHIZAKA, A ;
SHIRAKI, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (04) :666-671
[8]   Interfacial electronic structure of long-chain alkane/metal systems studied by UV-photoelectron and metastable atom electron spectroscopies [J].
Ito, E ;
Oji, H ;
Ishii, H ;
Oichi, K ;
Ouchi, Y ;
Seki, K .
CHEMICAL PHYSICS LETTERS, 1998, 287 (1-2) :137-142
[9]   Synthetic chemistry for ultrapure, processable, and high-mobility organic transistor semiconductors [J].
Katz, HE ;
Bao, ZN ;
Gilat, SL .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (05) :359-369
[10]   Control of face-to-face π-π stacked packing arrangement of anthracene rings via chalcogen-chalcogen interaction:: 9,10-bis(methylchalcogeno)anthracenes [J].
Kobayashi, K ;
Masu, H ;
Shuto, A ;
Yamaguchi, K .
CHEMISTRY OF MATERIALS, 2005, 17 (26) :6666-6673