Nitrogen and phosphorous co- doped graphitic carbon encapsulated ultrafine OsP2 nanoparticles: a pH universal highly durable catalyst for hydrogen evolution reaction

被引:22
作者
Chakrabartty, Sukanta [1 ]
Barman, Barun Kumar [1 ]
Raj, C. Retna [1 ]
机构
[1] Indian Inst Technol Kharagpur, Dept Chem, Funct Mat & Electrochem Lab, Kharagpur 721302, W Bengal, India
关键词
ELECTROCATALYSTS; DESIGN;
D O I
10.1039/c9cc00822e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis is described of a pH-universal hydrogen evolution electrocatalyst based on N and P co-doped graphitic carbon encapsulated OsP2 (OsP2@NPC) nanoparticles of 1.8 nm size for the electrocatalytic hydrogen evolution reaction (HER). Our OsP2-based catalyst is catalytically active at all pH values and delivers the benchmark current density of 10 mA cm(-2) at an overpotential of 46, 90 and 144 mV in acidic, alkaline and neutral pH, respectively.
引用
收藏
页码:4399 / 4402
页数:4
相关论文
共 30 条
[1]   Energy resources and global development [J].
Chow, J ;
Kopp, RJ ;
Portney, PR .
SCIENCE, 2003, 302 (5650) :1528-1531
[2]   Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H [J].
Conway, BE ;
Tilak, BV .
ELECTROCHIMICA ACTA, 2002, 47 (22-23) :3571-3594
[3]   Al-Doped Ni2P nanosheet array: a superior and durable electrocatalyst for alkaline hydrogen evolution [J].
Du, Huitong ;
Xia, Lian ;
Zhu, Shuyun ;
Qu, Fei ;
Qu, Fengli .
CHEMICAL COMMUNICATIONS, 2018, 54 (23) :2894-2897
[4]   High-Performance Rh2P Electrocatalyst for Efficient Water Splitting [J].
Duan, Haohong ;
Li, Dongguo ;
Tang, Yan ;
He, Yang ;
Ji, Shufang ;
Wang, Rongyue ;
Lv, Haifeng ;
Lopes, Pietro P. ;
Paulikas, Arvydas P. ;
Li, Haoyi ;
Mao, Scott X. ;
Wang, Chongmin ;
Markovic, Nenad M. ;
Li, Jun ;
Stamenkovic, Vojislav R. ;
Li, Yadong .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) :5494-5502
[5]   Electrocatalysts for hydrogen evolution reaction [J].
Eftekhari, Ali .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (16) :11053-11077
[6]   Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions [J].
Jiao, Yan ;
Zheng, Yao ;
Jaroniec, Mietek ;
Qiao, Shi Zhang .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (08) :2060-2086
[7]   Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends [J].
Kibsgaard, Jakob ;
Tsai, Charlie ;
Chan, Karen ;
Benck, Jesse D. ;
Norskov, Jens K. ;
Abild-Pedersen, Frank ;
Jaramillo, Thomas F. .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (10) :3022-3029
[8]   Powering the planet: Chemical challenges in solar energy utilization [J].
Lewis, Nathan S. ;
Nocera, Daniel G. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (43) :15729-15735
[9]   Porous superstructures constructed from ultrafine FeP nanoparticles for highly active and exceptionally stable hydrogen evolution reaction [J].
Lin, Chong ;
Gao, Zhengfei ;
Yang, Jianhui ;
Liu, Bin ;
Jin, Jian .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (15) :6387-6392
[10]   CoP nanoparticles anchored on N, P-dual-doped graphene-like carbon as a catalyst for water splitting in non-acidic media [J].
Liu, Yanyan ;
Zhu, Yihua ;
Shen, Jianhua ;
Huang, Jianfei ;
Yang, Xiaoling ;
Li, Chunzhong .
NANOSCALE, 2018, 10 (05) :2603-2612