Carbones and Carbon Atom as Ligands in Transition Metal Complexes

被引：48

作者：

Zhao, Lili ^{[1
]}

Chai, Chaoqun ^{[1
]}

Petz, Wolfgang ^{[2
]}

Frenking, Gernot ^{[1
,2
]}

机构：

[1] Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Nanjing 211816, Peoples R China

[2] Philipps Univ Marburg, Fachbereich Chem, Hans Meerwein Str 4, D-35043 Marburg, Germany

来源：

MOLECULES | 2020年 / 25卷 / 21期

基金：

中国国家自然科学基金;

关键词：

carbone complexes; carbido complexes; transition metal complexes; chemical bonding; VALENT FISCHER-TYPE; CARBENE COMPLEXES; CRYSTAL-STRUCTURE; ORGANOMETALLIC COMPOUNDS; CARBIDO COMPLEXES; PINCER LIGAND; CARBODIPHOSPHORANE PH3P=C=PPH3; SUBSTITUTED CARBODIPHOSPHORANE; STRUCTURAL-CHARACTERIZATION; CYCLIC CARBODIPHOSPHORANES;

D O I：

10.3390/molecules25214943

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (sigma and pi) donation to the metal atom [M]paired left arrows CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 -> [M]-CR2 -> [M]-CR -> [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.

引用

页数：48

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