Recent advances in asymmetric nitroso Diels-Alder reactions

被引：175

作者：

Yamamoto, Yuhei

Yamamoto, Hisashi

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

[2] Banyu Pharmaceut Co Ltd, Proc Res, Okazaki, Aichi 4440858, Japan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 2006卷 / 09期

关键词：

nitroso compounds; Diels-Alder reactions; asymmetric catalysis; amino alcohols; natural product synthesis;

D O I：

10.1002/ejoc.200500847

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During the past decade, the nitroso Diels-Alder (NDA) reaction has become more practical tool for organic synthesis, and a numbers of important compounds have been synthesized using this method. Until recently, no reports on a catalytic asymmetric version of this reaction had been reported; the major issues were the high reactivity of nitroso compounds and their chemical properties. This microreview outlines recent advances in the area of asymmetric NDA reaction following the review by Streith and Defoin in 1994.

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页码：2031 / 2043

页数：13

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