Laser jet spectra of methyl 3-chlorobenzoate

被引：3

作者：

Hirano, A ^{[1
]}

Tsumanuma, H ^{[1
]}

Kishi, K ^{[1
]}

Egawa, T ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 701卷 / 1-3期

关键词：

methyl; 3-chlorobenzoate; laser jet spectroscopy; REMPI spectrum; fluorescent excitation spectrum; intersystem crossing;

D O I：

10.1016/j.molstruc.2004.05.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The (1 + 1) REMPI spectrum and the fluorescence excitation spectrum of methyl 3-chlorobenzoate were measured in the supersonic free jet. In the fluorescence excitation spectrum, only one strong 0-0 band along with a few vibronic bands was observed although this compound has two stable conformers. In the REMPI spectrum, the 0-0 band of the other conformer and many vibronic bands in addition to the bands appearing in the fluorescence excitation spectrum were observed. This phenomenon can be explained by means of the conformational difference in the rate of the intersystem crossing between the S-1 and a triplet states. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：9 / 11

页数：3

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