Mossbauer study of hexavalent iron compounds

被引：20
|
作者：
Dedushenko, SK
Perfiliev, YD
Goldfeld, MG
Tsapin, AI
机构：
[1] Bauman Moscow State Tech Univ, Moscow 107005, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[3] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA
[4] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA
来源：
HYPERFINE INTERACTIONS | 2001年 / 136卷 / 3-8期
关键词：
ferrate(VI); Mossbauer spectra;
D O I：
10.1023/A:1020541910373
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Six crystalline ferrates(VI): K3Na(FeO4)(2),K2FeO4,Rb2FeO4,Cs2FeO4,K2Sr(FeO4)(2) and BaFeO4, were studied by Mossbauer spectroscopy. Room-temperature spectra of potassium, rubidium and cesium ferrates are single lines, but spectra of barium, potassium-strontium and potassium-sodium ferrates show a presence of quadrupole interactions. Most of these salts display an antiferromagnetic transition with a Neel temperature within 2 to 8 K range.
引用
收藏
页码：373 / 377
页数：5
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