Highly selective detection of saturated vapors of abused drugs by ZnO nanorod bundles gas sensor

被引:45
作者
Gao, Rui [1 ]
Cheng, Xiaoli [1 ]
Gao, Shan [1 ]
Zhang, Xianfa [1 ]
Xu, Yingming [1 ]
Zhao, Hui [1 ]
Huo, Lihua [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Minist Educ, Harbin 150080, Heilongjiang, Peoples R China
基金
对外科技合作项目(国际科技项目); 中国国家自然科学基金;
关键词
ZnO nanorod bundle gas sensors; Selectivity; Saturated vapors of abused drugs; ORAL FLUID; THIN-FILMS; METHAMPHETAMINE; MICROEXTRACTION; AMPHETAMINE; SPECTROMETRY; EXTRACTION;
D O I
10.1016/j.apsusc.2019.04.189
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is very necessary to quickly and selectively detect the abused drugs in real time, because of their bad influence on the central nervous system. So ZnO nanorod bundles were prepared by simple hydrothermal reaction combined with calcination in this paper, which were assembled into thick film gas sensor to detect three analogs of drugs. Such ZnO nanorod bundles gas sensor exhibited not only good gas response and selectivity, but also good reproducibility and stability to the saturated vapors of three kinds of drugs (C10H15NO, C9H13NO, C8H9NO2) at 252 degrees C. The excellent gas response can be ascribed to its rough surface and the large number of holes formed by nanorod bundles accumulation, which are conducive to diffusion, adsorption and desorption of gas molecules on ZnO nanorods. The reaction mechanism was further analyzed and discussed by XPS.
引用
收藏
页码:266 / 273
页数:8
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