A novel homodinuclear manganese(III) complex with N,N′-bis(salicylidene)diethylenetriamine: Synthesis, structure and catalytic activity

被引：9
|
作者：
Hosseini-Monfared, Hassan [1 ]
Alavi, Sohaila [1 ]
Mayer, Peter [2 ]
机构：
[1] Univ Zanjan, Dept Chem, Zanjan 45195313, Iran
[2] Univ Munich, Fak Chem & Pharm, D-81377 Munich, Germany
来源：
INORGANICA CHIMICA ACTA | 2014年 / 419卷
关键词：
Homodinuclear; Manganese; Structure; Catalysis; Oxidation; HYDROGEN-PEROXIDE; CRYSTAL-STRUCTURE; OXIDATION CATALYSTS; CONTAINING LIGANDS; CU(II) COMPLEXES; HIGHLY EFFICIENT; SALEN COMPLEXES; PI-STACKING; EPOXIDATION; ACID;
D O I：
10.1016/j.ica.2014.05.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel chloride bridged dinuclear manganese(III) complex was prepared and its structure established by X-ray diffraction analysis. The complex showed high selectivity in H2O2 promoted oxidation of cyclohexane and cyclic alkenes. Under optimized conditions, 72% of cyclohexane conversion with 85% of selectivity for alcohol was achieved after 5 h. To the best of our knowledge this activity and remarkable selectivity to cyclohexanol is the highest for a manganese catalyst. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：89 / 95
页数：7
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