Electrospray ionization mass spectrometry of stable nitroxide free radicals and two isoindoline nitroxide dimers

被引:0
作者
Smith, CD [1 ]
Bartley, JP [1 ]
Bottle, SE [1 ]
Micallef, AS [1 ]
Reid, DA [1 ]
机构
[1] Queensland Univ Technol, Sch Phys Sci, CIDC, Brisbane, Qld 4001, Australia
来源
JOURNAL OF MASS SPECTROMETRY | 2000年 / 35卷 / 05期
关键词
electrospray ionization; nitroxides; isoindoline; free radicals; biradicals;
D O I
10.1002/(SICI)1096-9888(200005)35:5<607::AID-JMS967>3.3.CO;2-Z
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Electrospray ionization (ESI) mass spectra were recorded for a range of substituted isoindoline nitroxides, two isoindoline nitroxide dimers and two piperidinyl nitroxides, In all cases the dominant molecular species arise from oxidation rather than protonation, an unusual process in ESI, Fragment ion spectroscopy was used to establish fragmentation mechanisms for the nitroxides under ESI conditions, Copyright (C) 2000 John Wiley & Sons, Ltd.
引用
收藏
页码:607 / 611
页数:5
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