Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(I) nitrene transfer catalysts

被引：55

作者：

Hamilton, CW ^{[1
]}

Laitar, DS ^{[1
]}

Sadighi, JP ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b404515g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New 1,10-phenanthroline ligands have been synthesized with C6F5 - or 2,4,6-(CF3)(3)C6H2- groups in the 2- and 9-positions; a cationic copper(I) complex of the latter catalyses nitrene transfer to the C - H bonds of electron-rich arenes.

引用

页码：1628 / 1629

页数：2

共 19 条

[1]

Bench BA, 2002, ANGEW CHEM INT EDIT, V41, P750, DOI 10.1002/1521-3773(20020301)41:5<750::AID-ANIE750>3.0.CO

[2]

2-6

[3] POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS .17. 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLLITHIUM, A STERICALLY CROWDED SYSTEM [J].

CARR, GE ;

CHAMBERS, RD ;

HOLMES, TF ;

PARKER, DG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) :13-23

[4] Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3Cu(NCMe) [J].

Díaz-Requejo, MM ;

Belderraín, TR ;

Nicasio, MC ;

Trofimenko, S ;

Pérez, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (40) :12078-12079

[5] FLUORINE RESONANCE SPECTRA OF PENTAFLUOROPHENYL ZINC HALIDES AND PENTAFLUOROPHENYL CADMIUM HALIDES [J].

EVANS, DF ;

PHILLIPS, RF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (09) :978-981

[6] Rapid catalytic oxygenation of hydrocarbons by ruthenium pentafluorophenylporphyrin complexes: Evidence for the involvement of a Ru(III) intermediate [J].

Groves, JT ;

Bonchio, M ;

Carofiglio, T ;

Shalyaev, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (37) :8961-8962

[7] Catalytic methods for C-H bond functionalization: Application in organic synthesis [J].

Kakiuchi, F ;

Chatani, N .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (9-10) :1077-1101

[8] Understanding and exploiting C-H bond activation [J].

Labinger, JA ;

Bercaw, JE .

NATURE, 2002, 417 (6888) :507-514

[9] Copper(I) complexes of a heavily fluorinated β-diketiminate ligand:: Synthesis, electronic properties, and intramolecular aerobic hydroxylation [J].

Laitar, DS ;

Mathison, CJN ;

Davis, WM ;

Sadighi, JP .

INORGANIC CHEMISTRY, 2003, 42 (23) :7354-7356

[10]

Loren JC, 2001, ANGEW CHEM INT EDIT, V40, P754, DOI 10.1002/1521-3773(20010216)40:4<754::AID-ANIE7540>3.0.CO

← 1 2 →