Stereoselective Cross-Coupling between Allylic Alcohols and Aldimines

被引：20

作者：

Lysenko, Ivan L. ^{[1
]}

Lee, Hyung Goo ^{[1
]}

Cha, Jin Kun ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 14期

关键词：

CATALYZED ASYMMETRIC ALLYLATION; ORGANOMETALLIC REAGENTS; ENANTIOSELECTIVE ALLYLATION; HOMOALLYLIC AMINES; IMINES; ALKYLATION;

D O I：

10.1021/ol901006c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cross-coupling reaction between an allylic alcohol and an imine is described for stereoselective allylation of aromatic and aliphatic imines. This method provides operationally simple, enantioselective access to functionalized homoallylic amines. Particularly noteworthy is direct use of a functionalized allylic alcohol as an allylating reagent without prederivatization, which obviates the use of preformed organometallic reagents or activated imine derivatives.

引用

页码：3132 / 3134

页数：3

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