ZINC(II) AND CADMIUM(II) COMPLEXES WITH o-HYDROXYBENZOIC ACID OR o-AMINOBENZOIC ACID AND 2-METHYLIMIDAZOLE IR spectra, X-ray diffraction studies and thermal analysis

被引：13

作者：

Olczak-Kobza, Maria ^{[1
]}

Mrozek, Agnieszka ^{[1
]}

机构：

[1] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2009年 / 96卷 / 02期

关键词：

aromatic acid; cadmium(II); heteroligand complexes; 2-methylimidazole; thermal analysis; zinc(II); COPPER(2) COMPLEXES; IMIDAZOLE; DERIVATIVES; DECOMPOSITION; NICKEL(2); CO(II); NI(II);

D O I：

10.1007/s10973-008-9048-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Mixed complexes of the type: Zn(Hsal)(2)(2-MeHim)(2), Zn(Han)(2)(2-MeHim)(2), Cd(Hsal)(2)(2-MeHim)(2), Cd(Han)(2)(2-MeHim)(2), where Hsal=OHC6H4COO-, Han=NH2C6H4COO-, 2-MeHim=2-methylimidazol) have been synthesized and characterized by IR spectroscopic and X-ray diffraction studies. Single-crystal X-ray structure of Cd(Hsal)(2)(2-MeHim)(2) has been obtained. Thermal behaviour of the compounds was investigated by thermal analysis (TG, DTG, DTA). A coupled TG-MS system was used to analyse the principal volatile products of complexes. Thermal decomposition pathways have been postulated.

引用

页码：553 / 560

页数：8

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