Iridium-Catalyzed Hydrogenation of Carboxylic Acid Esters

被引：65

作者：

Junge, Kathrin ^{[1
]}

Wendt, Bianca ^{[1
]}

Jiao, Haijun ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2014年 / 6卷 / 10期

关键词：

alcohols; esters; homogeneous catalysis; hydrogenation; iridium; IRON PINCER COMPLEX; EFFICIENT HYDROGENATION; ALCOHOLS; RUTHENIUM; MILD; REDUCTION; NITRILES; LIGANDS;

D O I：

10.1002/cctc.201402421

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first selective iridium-catalyzed hydrogenations of esters are presented. By using a commercially available iridium pincer complex more than 20 different aromatic, aliphatic, and (hetero)cyclic esters are reduced to the corresponding alcohols in moderate to very good yields. An outer-sphere mechanism is proposed on the basis of our computational analysis.

引用

页码：2810 / 2814

页数：5

共 41 条

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Alberico E., 2013, Angew. Chem., V125, P14412

[2] Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions [J].