Selective hydrogenation of o-glucose to o-sorbitol over HY zeolite supported ruthenium nanoparticles catalysts

被引：67
|
作者：
Mishra, Dinesh Kumar [1 ]
Dabbawala, Aasif Asharaf [1 ]
Park, Jung Je [1 ]
Jhung, Sung Hwa [2 ,3 ]
Hwang, Jin-Soo [1 ]
机构：
[1] Korea Res Inst Chem Technol, Biorefinery Res Ctr, Taejon 305600, South Korea
[2] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea
[3] Kyungpook Natl Univ, Green Nano Mat Res Ctr, Taegu 702701, South Korea
来源：
CATALYSIS TODAY | 2014年 / 232卷
关键词：
ID-Glucose u-Sorbitol Hydrogenation HY zeolite; Ruthenium nanoparticles; AMORPHOUS ALLOY CATALYST; LIQUID-PHASE DEHYDRATION; RANEY-TYPE NI; CONVERSION; BIOMASS; NICKEL; ACID; HYDROLYSIS; CHEMICALS; XYLOSE;
D O I：
10.1016/j.cattod.2013.10.018
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
HY zeolite (HYZ) supported ruthenium (Ru) nanoparticles catalyst (Ru/HYZ) is prepared by simple impregnation method and is characterized by using energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), CO chemisorption and inductively coupled plasma (ICP) mass spectrometry. The catalyst Ru/HYZ is evaluated in hydrogenation of D-glucose and hydrogenation experiments to produce a selective product D-sorbitol were conducted batch wise in a three-phase laboratory scale reactor. The kinetics studies of D-glucose hydrogenation using the catalyst Ru/HYZ were carried out. In the operating regime studied the rate of reaction showed first orders dependency with respect to D-glucose and hydrogen. For affording maximum D-glucose conversion, yield and selectivity to D-sorbitol, the reaction conditions were also optimized. C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：99 / 107
页数：9
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