In the (adsorption) competition between NOM and MIB, who is the winner, and why?

被引:9
作者
Newcombe, G [1 ]
Morrison, J [1 ]
Hepplewhite, C [1 ]
Knappe, DRU [1 ]
机构
[1] Australian Water Qual Ctr, Salisbury, SA 5108, Australia
来源
2ND WORLD WATER CONGRESS: DRINKING WATER TREATMENT | 2002年 / 2卷 / 02期
关键词
activated carbon; adsorption; MIB; tastes and odours;
D O I
10.2166/ws.2002.0046
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The adsorption of an odour compound common in drinking water, 2-methylisoborneol (MIB), was studied on four activated carbons in the presence of six well characterised natural organic matter (NOM) solutions. It was found that, although the carbons and the NOM solutions Had a wide range of characteristics, the major competitive mechanism was the same in all cases. The low molecular weight NOM compounds were the most competitive, participating in a direct competition with the MIB molecule for adsorption sites. Equivalent background concentration (EBC) calculations indicated a relatively low concentration of directly competing compounds in the NOM. Some evidence of pore blockage, and or restriction was also seen, with microporous carbons most affected by low molecular weight NOM, and mesoporous carbons impacted by the higher molecular weight compounds.
引用
收藏
页码:59 / 67
页数:9
相关论文
共 17 条
[1]   Experimental evaluation of cationic polyelectrolytes for removing natural organic matter from water [J].
Bolto, B ;
Abbt-Braun, G ;
Dixon, D ;
Eldridge, R ;
Frimmel, F ;
Hesse, S ;
King, S ;
Toifl, M .
WATER SCIENCE AND TECHNOLOGY, 1999, 40 (09) :71-79
[2]  
CHUDYK WA, 1979, J AM WATER WORKS ASS, V71, P529
[3]   The application of powdered activated carbon for MIB and geosmin removal: Predicting PAC doses in four raw waters [J].
Cook, D ;
Newcombe, G ;
Sztajnbok, P .
WATER RESEARCH, 2001, 35 (05) :1325-1333
[4]   SIMPLIFIED COMPETITIVE EQUILIBRIUM ADSORPTION MODEL [J].
DIGIANO, FA ;
BALDAUF, G ;
FRICK, B ;
SONTHEIMER, H .
CHEMICAL ENGINEERING SCIENCE, 1978, 33 (12) :1667-1673
[5]   Pore distribution effect of activated carbon in adsorbing organic micropollutants from natural water [J].
Ebie, K ;
Li, FS ;
Azuma, Y ;
Yuasa, A ;
Hagishita, T .
WATER RESEARCH, 2001, 35 (01) :167-179
[6]   Micropore size distribution of activated carbon fiber using the density functional theory and other methods [J].
El-Merraoui, M ;
Aoshima, M ;
Kaneko, K .
LANGMUIR, 2000, 16 (09) :4300-4304
[7]  
HEPPLEWHITE C, 2000, THESIS U S AUSTR AUS
[8]  
JAIN JS, 1973, J WATER POLLUT CON F, V45, P2463
[9]   Predicting the capacity of powdered activated carbon for trace organic compounds in natural waters [J].
Knappe, DRU ;
Matsui, Y ;
Snoeyink, VL ;
Roche, P ;
Prados, MJ ;
Bourbigot, MM .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1998, 32 (11) :1694-1698
[10]  
LALEZARY S, 1985, P ANN AWWA C WASH DC, P1007