Synthesis of a sulfonamide-Schiff base ligand and its Cu(II), Fe(III) and Co(III) complexes

被引：11

作者：

Chen, Fei ^{[1
]}

Askari, Mohammad S. ^{[1
]}

Ottenwaelder, Xavier ^{[1
]}

机构：

[1] Concordia Univ, Dept Chem & Biochem, Montreal, PQ H4B 1R6, Canada

来源：

INORGANICA CHIMICA ACTA | 2013年 / 407卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

Schiff base; Sulfonamide; Metal complexes; X-ray crystallography; CRYSTAL-STRUCTURES; SALEN;

D O I：

10.1016/j.ica.2013.07.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unsymmetric ligand bearing a salicylimine side and a 2-nitrobenzenesufonamide side has been synthesized in two simple steps. Complexations with Cu(II), Fe(III) and Co(II) - which oxidizes to Co(III) once complexed - indicate that the ligand can be either bidentate or tridentate depending on the geometric preferences of the metal ion and whether the sulfonamide is deprotonated. The obtained crystal structures are also stabilized via hydrogen bonds and pi-pi stacking interactions. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.

引用

页码：25 / 30

页数：6

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