Optical and structural properties of CuSbS2 thin films grown by thermal evaporation method

被引：95

作者：

Rabhi, A. ^{[1
]}

Kanzari, M. ^{[1
]}

Rezig, B. ^{[1
]}

机构：

[1] Lab Photovolta & Mat Semiconducteurs ENIT, Tunis 1002, Tunisia

来源：

THIN SOLID FILMS | 2009年 / 517卷 / 07期

关键词：

CuSbS2; Structural properties; Optical properties; DEPOSITION;

D O I：

10.1016/j.tsf.2008.11.021

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Structural, optical and electrical properties of CuSbS2 thin films grown by thermal evaporation have been studied relating the effects of substrate heating conditions of these properties. The CuSbS2 thin films were carried out at substrate temperatures in the temperature range 100-200 degrees C. The structure and composition were characterized by XRD, SEM and EDX. X-ray diffraction revealed that the films are (111) oriented upon substrate temperature 170 degrees C and amorphous for the substrate temperatures below 170 degrees C. No secondary phases are observed for all the films. The optical absorption coefficients and band gaps of the films were estimated by optical transmission and reflection measurements at room temperature. Strong absorption coefficients in the range 10(5)-10(6) cm(-1) at 500 nm were found. The direct gaps Eg lie between 0.91-1.89 eV range. It is observed that there is a decrease in optical band gap Eg with increasing the substrate temperature. Resistivity of 0.03-0.96 Omega cm, in dependence on substrate temperature was characterized. The all unheated films exhibit p-type conductivity. The characteristics reported here also offer perspective for CuSbS2 as an absorber material in solar cells applications. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2477 / 2480

页数：4

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