Temperature-Dependent Properties of nc-Si Thin Films Synthesized in Low-Pressure, Thermally Nonequilibrium, High-Density Inductively Coupled Plasmas

Silicon thin films were synthesized simultaneously on single-crystal silicon and glass substrates by low-pressure, thermally nonequilibrium, high-density inductively coupled plasma-assisted chemical vapor deposition from the silane precursor gas without any additional hydrogen dilution in a broad range of substrate temperatures from 100 to 500 degrees C. The effect of the Substrate temperature oil the morphological, Structural and optical properties of the synthesized silicon thin films is systematically Studied by X-ray diffractometry, Raman spectroscopy, UV-vis spectroscopy, and scanning electron microscopy. It is shown that the formation of nanocrystalline silicon (nc-Si) occurs when the Substrate temperature is higher than 200 degrees C and that all the deposited nc-Si films have a preferential growth along the (111) direction. However, the mean grain size of the (111) orientation slightly and gradually decreases while the mean grain size of the (220) orientation shows a monotonous increase with the increased Substrate temperature from 200 to 500 degrees C. It is also Found that the crystal volume fraction of the synthesized nc-Si thin films has a maximum value of similar to 69.1% at a substrate temperature of 300 rather than 500 degrees C. This rather unexpected result is interpreted through the interplay of thermokinetic surface diffusion and hydrogen termination effects. Furthermore, we have also shown that with the increased Substrate temperature from 100 to 500 degrees C, the optical bandgap is reduced while the growth rates tend to increase. The maximum rates of change of the optical bandgap and the growth rates Occur when the Substrate temperature is increased from 400 to 500 degrees C. These results are highly relevant to the development of photovoltaic thin-film solar cells, thin-film transistors, and flat-panel displays.