Dimeric & Polymeric Chiral Schiff Base Complexes and Supported BINOL Complexes as Potential Recyclable Catalysts in Asymmetric Kinetic Resolution and C-C Bond Formation Reactions

被引：10
作者：
Abdi, S. H. R. [1 ]
Kureshy, R. I. [1 ]
Khan, N. H. [1 ]
Mayani, V. J. [1 ]
Bajaj, H. C. [1 ]
机构：
[1] Cent Salt & Marine Chem Res Inst, Discipline Inorgan Mat & Catalysis, Council Sci & Ind Res, Bhavnagar 364002, Gujarat, India
来源：
CATALYSIS SURVEYS FROM ASIA | 2009年 / 13卷 / 02期
关键词：
Dimeric and polymeric chiral Schiff bases; BINOL; Asymmetric catalysis; Kinetic resolution; Racemic and meso epoxides; Asymmetric C-C bond formation; Nitro-Aldol reaction; Cyanation reaction; MN(III) SALEN COMPLEXES; OPTICALLY-ACTIVE CYANOHYDRINS; RACEMIC SECONDARY ALCOHOLS; RING-OPENING REACTIONS; BETA-AMINO ALCOHOLS; ENANTIOSELECTIVE CYANOSILYLATION; MESO-EPOXIDES; AROMATIC-AMINES; STEREOSELECTIVE-SYNTHESIS; TRIMETHYLSILYL CYANIDE;
D O I：
10.1007/s10563-009-9071-y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review is based on dimeric and polymeric chiral Schiff base metal complexes and chiral BINOL supported metal complexes as potential recyclable catalysts for kinetic resolution of racemic and meso epoxide and asymmetric C-C bond formation reactions e.g., asymmetric addition of diethylzinc to aldehydes, enantioselective addition of phenylacetylene to aldehydes, asymmetric nitro-Aldol reactions and asymmetric cyanation reaction.
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收藏
页码：104 / 131
页数：28
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