Controlled copolymerization of acrylonitrile in bulk via the reversible addition-fragmentation chain-transfer mechanism

被引：11
|
作者：
Chernikova, E. V. [1 ]
Poteryaeva, Z. A. [1 ]
Plutalova, A. V. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia
来源：
POLYMER SCIENCE SERIES B | 2014年 / 56卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
CONTROLLED RADICAL POLYMERIZATION; RAFT POLYMERIZATION; TRANSFER AGENTS; TRITHIOCARBONATES;
D O I：
10.1134/S1560090414020031
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The pseudoliving radical binary copolymerization of acrylonitrile with methyl acrylate, styrene, n-butyl acrylate, and tert-butyl acrylate in bulk in the presence of the reversible addition-fragmentation chain-transfer agent dibenzyl trithiocarbonate is performed for the first time. The addition of trithiocarbonate makes it possible to prepare a narrowly dispersed visually optically transparent copolymer in a wide range of monomer-feed compositions even at limiting conversions. Conditions for the synthesis of acrylonitrile copolymers with controlled molecular masses and narrow molecular-mass distributions are ascertained. In the above copolymers, the trithiocarbonate group is shown to be located within the chain.
引用
收藏
页码：109 / 117
页数：9
相关论文
共 50 条
  • [21] Reversible Thiyl Radical Addition-Fragmentation Chain Transfer Polymerization
    Wang, Yongjin
    Du, Jiaman
    Huang, Hanchu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (12)
  • [22] Reversible Addition-Fragmentation Chain Transfer Polymerization of Vinyl Chloride
    Abreu, Carlos M. R.
    Mendonca, Patricia V.
    Serra, Armenio C.
    Coelho, Jorge F. J.
    Popov, Anatoliy V.
    Gryn'ova, Ganna
    Coote, Michelle L.
    Guliashvili, Tamaz
    MACROMOLECULES, 2012, 45 (05) : 2200 - 2208
  • [23] Controlled synthesis of copolymers of vinyl acetate and n-butyl acrylate mediated by trithiocarbonates as reversible addition-fragmentation chain-transfer agents
    Chernikova, E. V.
    Yulusov, V. V.
    Mineeva, K. O.
    Garina, E. S.
    Sivtsov, E. V.
    POLYMER SCIENCE SERIES B, 2012, 54 (7-8) : 349 - 360
  • [24] Controlled Free-Radical Copolymerization of N-vinyl succinimide and n-Butyl acrylate via a Reversible Addition-Fragmentation Chain Transfer (RAFT) Technique
    Sivtsov, Eugene
    Chernikova, Elena
    Gostev, Alexey
    Garina, Elizaveta
    MODERN TRENDS IN POLYMER SCIENCE-EPF 09, 2010, 296 : 112 - +
  • [25] Star polymer synthesis using trithiocarbonate functional β-cyclodextrin cores (Reversible addition-fragmentation chain-transfer polymerization)
    Stenzel, MH
    Davis, TP
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (24) : 4498 - 4512
  • [26] Reversible Addition-Fragmentation Chain Transfer Polymerization from Surfaces
    Zhao, Youliang
    Perrier, Sebastien
    CONTROLLED RADICAL POLYMERIZATION AT AND FROM SOLID SURFACES, 2016, 270 : 77 - 106
  • [27] Enabling Reversible Addition-Fragmentation Chain-Transfer Polymerization for Brush Copolymers with a Poly(2-oxazoline) Backbone
    Kim, Jungyeon
    Cattoz, Beatrice
    Leung, Alice H. M.
    Parish, James D.
    Becer, C. Remzi
    MACROMOLECULES, 2022, 55 (11) : 4411 - 4419
  • [28] Molecular-Weight Distribution of Living Chains in Polystyrene Prepared by Reversible Addition-Fragmentation Chain-Transfer Polymerization
    Kim, Kyoungho
    Ahn, Junyoung
    Park, Mirim
    Lee, Hana
    Kim, Yeon Ji
    Chang, Taihyun
    Jeon, Heung Bae
    Paik, Hyun-jong
    MACROMOLECULES, 2019, 52 (19) : 7448 - 7455
  • [29] Rational Design of Biopolymers via Aqueous Reversible Addition-Fragmentation Chain Transfer Polymerization
    York, Stacey E.
    York, Adam W.
    McCormick, Charles L.
    POLYMERIC DELIVERY OF THERAPEUTICS, 2010, 1053 : 49 - 63
  • [30] Self-healing of thermoplastics via reversible addition-fragmentation chain transfer polymerization
    Yao, Li
    Rong, Min Zhi
    Zhang, Ming Qiu
    Yuan, Yan Chao
    JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (25) : 9060 - 9065
12345