Silver(I) perchlorate complexes of N,N′-bis(trans-cinnamaldehyde) ethylenediimine (ca2en)

被引：13
|
作者：
Khalaji, Aliakbar Dehno [1 ]
Aoki, Katsuyuki
Amirnasr, Mehdi
机构：
[1] Isfahan Univ Technol, Dept Chem, Esfahan 841568311, Iran
[2] Toyohashi Univ Technol, Dept Mat Sci, Tempaku Ku, Toyohashi, Aichi 4418580, Japan
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 02期
关键词：
schiff base; N; '-bis(trans-cinnamaldehyde)ethylenediimine; silver(I); crystal structure; spectroscopy;
D O I：
10.1080/00958970600763250
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three silver(I) complexes, [Ag(ca(2)en)(PPh3)]ClO4 (1), [Ag(ca(2)en)(PPh3)(2)]ClO4 (2) and [Ag(ca(2)en)(2)]ClO4 (3), where ca(2)en N, N'-bis(trans-cinnamaldehyde)ethylenediimine, have been synthesized and characterized spectroscopically. The crystal structure of ( 1) was determined by X-ray diffraction methods. Crystal data for 1: C38H35AgClN2O4P, triclinic, P1, a = 12.086(2), b = 18.204(2), c = 8.550(2) angstrom, alpha = 102.69(1), beta = 105.85(1), gamma = 91.47(1)degrees, V = 1758.0(5) angstrom(3), Z = 2, R(F) = 0.070, wR (F) 0.064, T = 296 K. The coordination geometry of the Ag atom is distorted trigonal involving two N atoms of ca(2)en and one P atom of triphenylphosphine (PPh3).
引用
收藏
页码：201 / 206
页数：6
相关论文
共 50 条
  • [41] Silver(I), nickel(II) N-heterocyclic carbene complexes based on bidentate bis-imidazolium salt with a quinoxaline linker: syntheses, structures, and characterization
    Xia, Changkun
    Yang, Kai
    Sun, Wen
    Lu, Xiaojing
    Xie, Jimin
    JOURNAL OF COORDINATION CHEMISTRY, 2017, 70 (04) : 615 - 625
  • [42] Synthesis, characterization, computational, conductometric titration and DNA binding studies of N′1,N′2-bis (3-hydroxy-5,5-dimethylcyclohex-2-en-1-ylidene) oxalohydrazide complexes
    Abu El-Reash, G. M.
    Zaky, R. R.
    El-Gamil, Mohammed M.
    El-Emam, S. M.
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 288
  • [43] Syntheses, Crystal Structure and Optical Property of Two Bis-ligand Silver(I) Complexes Containing Diphenic Acid and Bidentate N-donor Ligands
    Wang Chong-Chen
    Song Yan-Xia
    Wang Yuan-Lan
    Wang Peng
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2011, 27 (02) : 361 - 366
  • [44] Novel Silver(I) Ion Selective PVC Membrane Electrode Based on the Schiff Base (N2E,N2′E)-N2,N2′-Bis(Thiophen-2-ylmethylene)-1,1′-Binaphthyl-2,2′-Diamine
    Jeong, Eunseon
    Ahmed, Mohammad Shamsuddin
    Jeong, Haesang
    Lee, Eunhee
    Jeon, Seungwon
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (03) : 800 - 804
  • [45] Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-N1)bis(5,5-dimethyl-2,2-bipyridine-2N,N)copper(II) complexes with tetrafluoroborate and perchlorate anions
    Potocnak, Ivan
    Burcak, Milan
    Dusek, Michal
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2013, 69 : 1357 - +
  • [46] Synthesis and characterization of three mononuclear Fe(III) complexes containing bipodal and tripodal ligands:: X-ray molecular structure of the dichloro[N-propanamide-N,N-bis-(2-pyridylmethyl)amine]iron(III) perchlorate
    Carvalho, NMF
    Horn, A
    Bortoluzzi, AJ
    Drago, V
    Antunes, OAC
    INORGANICA CHIMICA ACTA, 2006, 359 (01) : 90 - 98
  • [47] Conformation Restriction of Nonplanar Di-2-pyrimidyl Sulfide with Intramolecular N•••C Interaction and Its Supramolecular Silver(I) Complexes
    Wan, Chong-Qing
    Wang, Zi-Jia
    Wang, Guo
    Liu, Hao
    Deng, Yu-Heng
    Jin, Qiong-Hua
    CRYSTAL GROWTH & DESIGN, 2012, 12 (01) : 376 - 386
  • [48] Crystal structure of bis(1,3-dimethoxyimidazolin-2-ylidene)silver(I) hexafluoridophosphate, N-heterocyclic carbene (NHC) complex
    Rietzler, Barbara
    Laus, Gerhard
    Kahlenberg, Volker
    Schottenberger, Herwig
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M251 - U353
  • [49] Synthesis, characterization, and biological evaluation of silver(I) complexes of N-(1-(pyrazin-2-yl)ethylidene)picolinohydrazide
    Ren, Qing-Ling
    Zhao, Shan-Shan
    Song, Lin-Xia
    Qian, Shao-Song
    Qin, Jie
    JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (02) : 227 - 237
  • [50] Theoretical Study of Energetic Complexes (III): Bis-(5-nitro-2H-tetrazolato-N2)tetraammine Cobalt(III) Perchlorate (BNCP) and Its Transition Metal (Ni/Fe/Cu/Zn) Perchlorate Analogues
    Shang Jing
    Zhang Jianguo
    Zhang Tonglai
    Huang Huisheng
    Zhang Shaowen
    Shu Yuanjie
    CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (07) : 1624 - 1630
12345