Silver(I) perchlorate complexes of N,N′-bis(trans-cinnamaldehyde) ethylenediimine (ca2en)

被引：13
|
作者：
Khalaji, Aliakbar Dehno [1 ]
Aoki, Katsuyuki
Amirnasr, Mehdi
机构：
[1] Isfahan Univ Technol, Dept Chem, Esfahan 841568311, Iran
[2] Toyohashi Univ Technol, Dept Mat Sci, Tempaku Ku, Toyohashi, Aichi 4418580, Japan
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 02期
关键词：
schiff base; N; '-bis(trans-cinnamaldehyde)ethylenediimine; silver(I); crystal structure; spectroscopy;
D O I：
10.1080/00958970600763250
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three silver(I) complexes, [Ag(ca(2)en)(PPh3)]ClO4 (1), [Ag(ca(2)en)(PPh3)(2)]ClO4 (2) and [Ag(ca(2)en)(2)]ClO4 (3), where ca(2)en N, N'-bis(trans-cinnamaldehyde)ethylenediimine, have been synthesized and characterized spectroscopically. The crystal structure of ( 1) was determined by X-ray diffraction methods. Crystal data for 1: C38H35AgClN2O4P, triclinic, P1, a = 12.086(2), b = 18.204(2), c = 8.550(2) angstrom, alpha = 102.69(1), beta = 105.85(1), gamma = 91.47(1)degrees, V = 1758.0(5) angstrom(3), Z = 2, R(F) = 0.070, wR (F) 0.064, T = 296 K. The coordination geometry of the Ag atom is distorted trigonal involving two N atoms of ca(2)en and one P atom of triphenylphosphine (PPh3).
引用
收藏
页码：201 / 206
页数：6
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