Silver(I) perchlorate complexes of N,N′-bis(trans-cinnamaldehyde) ethylenediimine (ca2en)

被引：13

作者：

Khalaji, Aliakbar Dehno ^{[1
]}

Aoki, Katsuyuki

Amirnasr, Mehdi

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 841568311, Iran

[2] Toyohashi Univ Technol, Dept Mat Sci, Tempaku Ku, Toyohashi, Aichi 4418580, Japan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 02期

关键词：

schiff base; N; '-bis(trans-cinnamaldehyde)ethylenediimine; silver(I); crystal structure; spectroscopy;

D O I：

10.1080/00958970600763250

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three silver(I) complexes, [Ag(ca(2)en)(PPh3)]ClO4 (1), [Ag(ca(2)en)(PPh3)(2)]ClO4 (2) and [Ag(ca(2)en)(2)]ClO4 (3), where ca(2)en N, N'-bis(trans-cinnamaldehyde)ethylenediimine, have been synthesized and characterized spectroscopically. The crystal structure of ( 1) was determined by X-ray diffraction methods. Crystal data for 1: C38H35AgClN2O4P, triclinic, P1, a = 12.086(2), b = 18.204(2), c = 8.550(2) angstrom, alpha = 102.69(1), beta = 105.85(1), gamma = 91.47(1)degrees, V = 1758.0(5) angstrom(3), Z = 2, R(F) = 0.070, wR (F) 0.064, T = 296 K. The coordination geometry of the Ag atom is distorted trigonal involving two N atoms of ca(2)en and one P atom of triphenylphosphine (PPh3).

引用

页码：201 / 206

页数：6

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