Visible-Light, Photoredox-Mediated Oxidative Tandem Nitroso-Diels-Alder Reaction of Arylhydroxylamines with Conjugated Dienes

被引：11

作者：

Santacroce, Veronica ^{[1
,3
]}

Duboc, Raphael ^{[1
]}

Malacria, Max ^{[1
,2
]}

Maestri, Giovanni ^{[3
]}

Masson, Geraldine ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris Sud, CNRS UPR 2301, Inst Chim Subst Nat, 1 Ave Terrasse, F-91198 Gif Sur Yvette, France

[2] UPMC Sorbonne Univ, IPCM, UMR CNRS 7201, 4 Pl Jussieu,C 229, F-75005 Paris, France

[3] Univ Parma, Dipartimento Chim, 17-A Parco Area Sci, I-43124 Parma, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 15期

关键词：

Photocatalysis; Oxidative tandem; Nitroso-Diels-Alder reaction; Radicals; Nitrogen heterocycles; CATALYZED AEROBIC OXIDATION; ACYLNITROSO ENE REACTION; HYDROXAMIC ACIDS; ACYL-NITROSO; ORGANIC-SYNTHESIS; SYNTHETIC APPLICATIONS; MECHANISTIC INSIGHTS; ARYLBORONIC ACIDS; COUPLING REACTION; MILD OXIDATION;

D O I：

10.1002/ejoc.201601492

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arylhydroxylamines were used in the nitroso-Diels-Alder reaction to generate in situ nitrosoarenes under visible-light, catalytic and aerobic conditions. Mixing a solution of aryl- or heteroarylhydroxylamines with conjuguated dienes in the presence of a catalytic amount of Ru(bpy)(3)Cl-2 afforded 3,6-dihydro-1,2-oxazines in good yields under an oxygen atmosphere.

引用

页码：2095 / 2098

页数：4

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