Enthalpic changes on mixing two couples of S- and R-enantiomers which contained amino groups at 298.15 K

被引：9

作者：

Kimura, T. ^{[1
]}

Khan, M. A. ^{[1
]}

Kamiyama, T. ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Technol, Dept Chem, Higashiosaka, Osaka 5778502, Japan

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2006年 / 85卷 / 03期

关键词：

2-aminobutan-1-ol; 2-aminoheptane; 2-aminohexane; 2-anminononane; 2-aminooctane; chiral compound; 1-(4-chlorophenyl)ethylamine; enthalpy of mixing; 1-(4-fluorophenyl)-ethylamine; R- and S-enantiomers;

D O I：

10.1007/s10973-006-7657-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Enthalpies of mixing of R- and S-enantiomers of liquid chiral compounds such as 2-aminohexane, 2-aminoheptane, 2-aminooctane, 2-aminononane, 1-( 4-chlorophenyl)-ethylamine, 1-(4-fluorophenyl) ethylamine, 2-amino-butane- 1-ol have been measured over the whole range of mole fractions at 298.15 K. Mixing of heterochiral liquids observed, realized enthalpic destabilization over entire compositions. The extreme values of enthalpies of mixing and the intermolecular interaction obtained by the molecular mechanics calculations showed a linear correlation, except the few compounds measured.

引用

页码：575 / 580

页数：6

共 20 条

[1] STATISTICAL THERMODYNAMICS OF SOLUTIONS OF OPTICALLY ACTIVE SUBSTANCES .1. EXCESS FREE ENERGY OF BINARY SOLUTION OF D-ISOMER AND L-ISOMER [J].

AMAYA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (11) :1689-1693

[2] STATISTICAL THERMODYNAMICS OF SOLUTIONS OF OPTICALLY ACTIVE SUBSTANCES .2. SOLUBILITY OF D-ISOMERS AND L-ISOMERS IN OPTICALLY ACTIVE SOLVENTS [J].

AMAYA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (12) :1803-1806

[3]

[Anonymous], 2003, GAUSS 03 REV B 03

[4] CHIRAL DISCRIMINATION IN LIQUIDS .2. EXCESS MOLAR ENTHALPIES OF ((1-X)A++XA-), WHERE A DENOTES FENCHONE OR ALPHA-METHYLBENZYLAMINE [J].

ATIK, Z ;

EWING, MB ;

MCGLASHAN, ML .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1983, 15 (02) :159-163

[5] CHIRAL DISCRIMINATION IN LIQUIDS - EXCESS MOLAR VOLUMES OF (1-X)A+ + XA, WHERE A DENOTES LIMONENE, FENCHONE, AND ALPHA-METHYLBENZYLAMINE [J].

ATIK, Z ;

EWING, MB ;

MCGLASHAN, ML .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (22) :3300-3303

[6]

GUETTE JP, 1973, TETRAHEDRON LETT, P465

[7]

*HYERCUBE INC, HYPCH VERS 7 01

[8] Enthalpic changes on mixing two couples of S- and R-enantiomers of benzyl-(1-phenyl-ethyl)-amine, 1-phenylethylamine, 1-phenyl-ethanol, butyric acid oxiranylmethyl ester, 4-methyl-[1,3]dioxolan-2-one, 2-chloro-methyloxirane and 3-hydroxyisobutyric acid methyl ester at T=298.15 K [J].

Kimura, T. ;

Khan, Mohammad A. ;

Ishii, Masakazu ;

Ueda, Kana ;

Matsushita, Takanori ;

Kamiyama, Tadashi ;

Fujisawa, Masao .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (08) :1042-1048

[9] Excess Enthalpies of {CH3(CH2)n=5 to 12} plus methyl methylthiomethyl sulfoxide or plus dimethyl sulfoxide at 298.15 K [J].

Kimura, T ;

Matsushita, T ;

Kamiyama, T ;

Takagi, S .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) :1046-1051

[10] Enthalpic changes on mixing two couples of S- and R-enantiomers of heptane-2-ol, octane-2-ol, nonane-2-ol, 3-chloro-propane-1,2-diol, 2-methyl-1,4-butanediol at 298.15 K [J].

Kimura, T ;

Matsushita, T ;

Ueda, K ;

Aktar, F ;

Matsuda, T ;

Kamiyama, T ;

Fujisawa, M .

THERMOCHIMICA ACTA, 2004, 414 (02) :209-214

← 1 2 →