A new moisture-sensitive metal-coordination solids {[Cd(C4O4)(bipy)(H2O)2]•3H2O}∞ (bipy=4,4′-bipyridine)

被引：18

作者：

Wang, CC ^{[1
]}

Yang, CH

Tseng, SM

Lee, GH

Sheu, HS

Phyu, KW

机构：

[1] Soochow Univ, Dept Chem, Taipei 111, Taiwan

[2] Natl Taiwan Univ, Instrumentat Ctr, Taipei 10764, Taiwan

[3] Natl Synchrotron Res Ctr, Hsinchu 30077, Taiwan

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 12期

关键词：

crystal structure; hydrothermal synthesis; metal-organic framework; Cd(II) polymer;

D O I：

10.1016/j.ica.2004.05.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mixed-ligands metal-coordination polymer, [Cd(C4O4)(bipy)(H2O2)(2)] (1), (bipy = 4,4'-bipyridine), was synthesized under hydrothermal condition and characterized by X-ray diffraction method. A three-dimensional interpenetrating network with one-dimensional channels intercalating water molecules undergoes a reversible hydration-dehydration process upon a cooling-heating cycles associated with distinct color change and structural variation. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3759 / 3764

页数：6

共 19 条

[1]

[Anonymous], 1995, SMART V 4 043 SOFTW

[2]

[Anonymous], 1995, SHELXTL 5 03 PC VERS

[3] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].