Direct metal-free synthesis of diarylamines from 2-nitropropane via the twofold C-H functionalization of arenes

被引：22

作者：

Aksenov, Alexander V. ^{[1
]}

Aksenov, Nicolai A. ^{[1
]}

Orazova, Naila A. ^{[1
]}

Aksenov, Dmitrii A. ^{[1
]}

Dmitriev, Maksim V. ^{[2
]}

Rubin, Michael ^{[1
,3
]}

机构：

[1] North Caucasus Fed Univ, Dept Chem, Stavropol 355009, Russia

[2] Perm State Univ, Dept Chem, Perm 614990, Russia

[3] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

RSC ADVANCES | 2015年 / 5卷 / 103期

基金：

俄罗斯基础研究基金会;

关键词：

ROOM-TEMPERATURE; 3-SUBSTITUTED; 2-QUINOLONES; ARYL CHLORIDES; CROWN-ETHERS; AMINATION; COMPLEXES; REAGENTS; ANILINES; DESIGN; NITROSOARENES;

D O I：

10.1039/c5ra17668a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of symmetric diarylamines via a twofold intermolecular electrophilic C-H functionalization of electron-rich arenes by umpolung-activated nitroalkane in polyphosphoric acid is demonstrated.

引用

页码：84849 / 84855

页数：7

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